Analytical Services: Optical Emission Spectroscopy
Paul B. Farnsworth, Department of Chemistry, Brigham Young University
|
General Use |
|---|
|
- Quantitative determination of major and trace elemental consituents in various sample types |
|
- Qualitative elemental analysis |
|
Examples of Applications |
|
- Rapid determination of concentrations of alloying elements in steels and other alloys |
|
- Elemental analysis of geological materials |
|
- Determination of trace impurity concentrations in semiconductor materials |
|
- Wear metals analysis in oils |
|
- Determination of alkali and alkaline earth concentrations in aqueous samples |
|
- Determination of calcium in cement |
|
Samples |
|
- Form: Conducting solids (arcs, sparks, glow discharges), powders (arcs), and solutions (flames) |
|
- Size: Depends on specific technique; from approximately 10 -6 g to several grams |
|
- Preparation: Machining or grinding (metals), dissolution (for flames), and digestion or ashing (organic samples) |
|
Limitations |
|
- Some elements are difficult or impossible to determine, such as nitrogen, oxygen, hydrogen, halogens, and noble gases |
|
- Sample form must be compatible with specific technique |
|
- All methods provide matrix-dependent responses |
|
Estimated Analysis Time |
|
- 30 s to several hours, depending on sample preparation requirements |
|
Capabilities of Related Techniques |
|
- X-ray fluorescence: Bulk and minor constituent
elemental analysis; requires sophisticated data reduction for
quantitative analysis; not useful for light elements (atomic
number |
|
- Inductively coupled plasma emission spectroscopy: Rapid quantitative elemental analysis with parts per billion detection limits; samples must be in solution; not useful for hydrogen, nitrogen, oxygen, halides, and noble gases |
|
- Direct-current plasma emission spectroscopy: Similar in performance to inductively coupled plasma emission spectroscopy |
|
- Atomic absorption spectroscopy: Favorable sensitivity and precision for most elements; single-channel technique; inefficient for multielement analysis |
Reprinted with permission of ASM International®.
Latest Resources
- January 31, 2010 - Corrosion Of Aluminum Hardware – Case History of Corrosion Of Aluminum Hardware
- June 25, 2009 - Case History: Wind Turbine Manufacturer –
Case history from Metallurgical Department of NHML.
- June 25, 2009 - Case History: Serrated Austenitic Screws – Case history from Metallurgical Department of NHML
- June 25, 2009 - Case History: Weld Exams – Case history from Materials Department of NHML
Latest Newsletters
- 05/01/2010 - Nuts & Bolts E-Newsletter Issue 4
- 11/01/2009 - Nuts & Bolts E-Newsletter Issue 3
- 07/01/2009 - Nuts & Bolts E-Newsletter Issue 2
- 01/01/2009 - Nuts & Bolts E-Newsletter Issue 1
