Analytical Services: Optical Emission Spectroscopy
Paul B. Farnsworth, Department of Chemistry, Brigham Young University
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General Use |
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- Quantitative determination of major and trace elemental consituents in various sample types |
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- Qualitative elemental analysis |
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Examples of Applications |
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- Rapid determination of concentrations of alloying elements in steels and other alloys |
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- Elemental analysis of geological materials |
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- Determination of trace impurity concentrations in semiconductor materials |
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- Wear metals analysis in oils |
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- Determination of alkali and alkaline earth concentrations in aqueous samples |
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- Determination of calcium in cement |
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Samples |
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- Form: Conducting solids (arcs, sparks, glow discharges), powders (arcs), and solutions (flames) |
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- Size: Depends on specific technique; from approximately 10 -6 g to several grams |
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- Preparation: Machining or grinding (metals), dissolution (for flames), and digestion or ashing (organic samples) |
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Limitations |
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- Some elements are difficult or impossible to determine, such as nitrogen, oxygen, hydrogen, halogens, and noble gases |
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- Sample form must be compatible with specific technique |
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- All methods provide matrix-dependent responses |
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Estimated Analysis Time |
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- 30 s to several hours, depending on sample preparation requirements |
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Capabilities of Related Techniques |
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- X-ray fluorescence: Bulk and minor constituent
elemental analysis; requires sophisticated data reduction for
quantitative analysis; not useful for light elements (atomic
number |
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- Inductively coupled plasma emission spectroscopy: Rapid quantitative elemental analysis with parts per billion detection limits; samples must be in solution; not useful for hydrogen, nitrogen, oxygen, halides, and noble gases |
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- Direct-current plasma emission spectroscopy: Similar in performance to inductively coupled plasma emission spectroscopy |
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- Atomic absorption spectroscopy: Favorable sensitivity and precision for most elements; single-channel technique; inefficient for multielement analysis |
Reprinted with permission of ASM International®.
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